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What are surfactants?

Consider an air / oil / water system :

The phases are immiscible due to tension at the surfaces. Surfactants reduce the tension and bring the phases together. On being added to the system (and agitated) oil disperses into water.

 

 
 

If more surfactant is added, solubilization of oil into water (transparent liquid) may result


 
 

 

How does a surfactant reduce surface tension?

A typical surfactant molecule has two groups with properties of opposite nature :

 

 
 

The two portions of the surfactant molecule are able to link together two dissimilar phases. What happens when a surfactant is added to an oil/water system?

Water in oil emulsions occur thus linking two phases

 
 
Example
     
 

Soil on cloth Dirt + oil (from perspiration) This is trapped in micelles when a detergent (surfactant) is added. It is emulsified and washed off. Surface tension is measured in dyne/cm.

Hg (mercury) has s.t. of 475 dyne/cm H2O (Water) has s.t. of 72 dyne/cm

 

 

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